European Journal of Organic Chemistry, volume 2001, issue 4, pages 697-706

3,6-Bis(2H-tetrazol-5-yl)-1,2,4,5-tetrazine: A Versatile Bifunctional Building Block for the Synthesis of Linear Oligoheterocycles

Jürgen Sauer 1
Gunther R Pabst 1
Uwe Holland 1
Hyun-Sook Kim 1
Stefan Loebbecke 2
Publication typeJournal Article
Publication date2001-02-01
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor2.8
ISSN1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
3,6-Bis(2H-tetrazol-5-yl)-1,2,4,5-tetrazine (3) (BTT) is an energy-rich compound and a strong dibasic acid. The bifunctional compound 3 is capable of [4+2] cycloadditions through its tetrazine unit as a 4π compound, and of acylating ring-opening reactions through its tetrazole rings, leading to the formation of linear oligoheterocycles 7, 12 with 1,2,4,5-tetrazine, pyridazine, 1,3,4-oxadiazole, thiophene, furan, and pyrrole units in sequences not easily available by other synthetic methods.

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GOST |
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GOST Copy
Sauer J. et al. 3,6-Bis(2H-tetrazol-5-yl)-1,2,4,5-tetrazine: A Versatile Bifunctional Building Block for the Synthesis of Linear Oligoheterocycles // European Journal of Organic Chemistry. 2001. Vol. 2001. No. 4. pp. 697-706.
GOST all authors (up to 50) Copy
Sauer J., Pabst G. R., Holland U., Kim H., Loebbecke S. 3,6-Bis(2H-tetrazol-5-yl)-1,2,4,5-tetrazine: A Versatile Bifunctional Building Block for the Synthesis of Linear Oligoheterocycles // European Journal of Organic Chemistry. 2001. Vol. 2001. No. 4. pp. 697-706.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/1099-0690(200102)2001:4<697::aid-ejoc697>3.0.co;2-n
UR - https://doi.org/10.1002/1099-0690(200102)2001:4<697::aid-ejoc697>3.0.co;2-n
TI - 3,6-Bis(2H-tetrazol-5-yl)-1,2,4,5-tetrazine: A Versatile Bifunctional Building Block for the Synthesis of Linear Oligoheterocycles
T2 - European Journal of Organic Chemistry
AU - Sauer, Jürgen
AU - Pabst, Gunther R
AU - Holland, Uwe
AU - Kim, Hyun-Sook
AU - Loebbecke, Stefan
PY - 2001
DA - 2001/02/01 00:00:00
PB - Wiley
SP - 697-706
IS - 4
VL - 2001
SN - 1434-193X
SN - 1099-0690
ER -
BibTex |
Cite this
BibTex Copy
@article{2001_Sauer,
author = {Jürgen Sauer and Gunther R Pabst and Uwe Holland and Hyun-Sook Kim and Stefan Loebbecke},
title = {3,6-Bis(2H-tetrazol-5-yl)-1,2,4,5-tetrazine: A Versatile Bifunctional Building Block for the Synthesis of Linear Oligoheterocycles},
journal = {European Journal of Organic Chemistry},
year = {2001},
volume = {2001},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/1099-0690(200102)2001:4<697::aid-ejoc697>3.0.co;2-n},
number = {4},
pages = {697--706},
doi = {10.1002/1099-0690(200102)2001:4<697::aid-ejoc697>3.0.co;2-n}
}
MLA
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MLA Copy
Sauer, Jürgen, et al. “3,6-Bis(2H-tetrazol-5-yl)-1,2,4,5-tetrazine: A Versatile Bifunctional Building Block for the Synthesis of Linear Oligoheterocycles.” European Journal of Organic Chemistry, vol. 2001, no. 4, Feb. 2001, pp. 697-706. https://doi.org/10.1002/1099-0690(200102)2001:4<697::aid-ejoc697>3.0.co;2-n.
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